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MS
unreviewed

Xanthine oxidoreductase (XOR / XDH-XO)

2 reactions · 1 pathways

Cofactors used

Clinical / pharmacological. Target of allopurinol and febuxostat; deficiency causes xanthinuria

What it does, reaction by reaction

2 reactions

Purine Degradation (to Uric Acid) Nucleotide Metabolism · Cytosol

step 6 Irreversible/directional

Hypoxanthine → xanthine

Converts Hypoxanthine into Xanthine

Notes

Xanthine oxidoreductase (XOR) catalyzes hypoxanthine + H2O + oxidized electron acceptor → xanthine + reduced electron acceptor. As xanthine dehydrogenase, XOR can transfer electrons to NAD+; as xanthine oxidase, it transfers electrons to O2, generating superoxide and/or H2O2. The molybdenum cofactor, FAD, and iron-sulfur centers are required.

step 7 Irreversible

Xanthine → uric acid (urate)

Converts Xanthine into Uric acid

Notes

XOR catalyzes xanthine + H2O + oxidized electron acceptor → uric acid + reduced electron acceptor. This is the terminal oxidation in humans and is effectively irreversible; uric acid is largely deprotonated to monosodium urate in extracellular fluid.

Showing all 2 reactions.

What accelerates and inhibits it

Regulation is pathway-specific, so each context is listed separately

1 entries

Purine Degradation (to Uric Acid)

Listed there as: Xanthine oxidoreductase

Accelerated by

Hypoxanthine/xanthine availability; conversion of dehydrogenase to oxidase can occur with oxidation/proteolysis

Inhibited by

Allopurinol (via oxypurinol), febuxostat, topiroxostat

Hormonal control

No dominant acute hormonal regulation; expression can rise with inflammatory and hypoxic/ischemic stress.

Recent literature

Europe PMC · from cache · sorted by publication date

  1. 1
  2. 2
    Benchmarking analytical parameters of chemiluminescent superoxide systems for robust quantification of graphene oxide redox activity.

    Chermashentsev GR, Poimenova IA, Ovseenko ST, Ratova DV, Proskurnina EV, Proskurnin MA, Mikheev IV. · 2026-06-03

    unreviewed
  3. 3
    Polydatin alleviates adenine-induced nephropathy in mice.

    Sheng T, Ma T, Jin X, Chen D, Che S, Wang J, Shen J, Shi C, Li Q, Sun Y, Chen D, Xu G. · 2026-05-31

    open access unreviewed
  4. 4
  5. 5
    Grass carp catalase inhibits GCRV replication through ROS scavenging-mediated immune suppression and autophagy.

    Wang X, Zou X, Liu L, Liang X, Wang H, Yang C, Li Y, Liao L, Zhu Z, Wang Y, Zhao J, He L. · 2026-06-02

    open access unreviewed
  6. 6
  7. 7
    Gut microbiota metabolic reprogramming drives the development of metabolic diseases in the host.

    Wang Y, Huang B, Wei X, Guan Y, Li L, Zheng Y, Sun W. · 2026-03-14

    cited 10× open access unreviewed
  8. 8
    The mouse gastric surface epithelial cell and its response to early <i>Helicobacter pylori</i> infection.

    Erhardsson M, Santos L, Benktander J, Sharba S, Thorell K, Lindén S. · 2026-03-25

    open access unreviewed
  9. 9
    Exploring the gut microbiome and metabolomic interactions of antimetabolite drugs to optimize therapy.

    Chen J, Wang Y, Xu L, Li X, Zhao L. · 2026-02-27

    open access unreviewed
  10. 10

External claims. These come from an index outside this database and are not checked against it. Treat them as leads.